Chemical structure of terrestrial humus materials formed from different vegetation characterized by solid-state 13C NMR with CP-MAS techniques
- 1 September 1990
- journal article
- Published by Wiley in European Journal of Soil Science
- Vol. 41 (3), 371-377
- https://doi.org/10.1111/j.1365-2389.1990.tb00072.x
Abstract
Eleven samples of terrestrial humus from different vegetational backgrounds were examined with solid‐state 13C NMR using cross‐polarization and magic‐angle spinning (CP‐MAS). In addition, all the samples were run with a dipolar dephasing pulse sequence for non‐quarternary carbon suppression (NQS). The humus samples all appeared to contain small amounts of aromatic substances and larger amounts of aliphatic compounds. Most of the samples contained considerable amounts of hydroxyl groups and acetals, which originate mainly from carbohydrates. No correlations were found between vegetational background and chemical structure.Keywords
This publication has 18 references indexed in Scilit:
- ATTEMPTS TO IMPROVE SOLID STATE 13C NMR SPECTRA OF WHOLE MINERAL SOILSCanadian Journal of Soil Science, 1988
- Spinning sideband suppression and quantitative analysis in solid state 13C n.m.r. of fossil fuelsFuel, 1987
- Litter decomposition and humification in acidic forest soils studied by chemical degradation, IR and NMR spectroscopy and pyrolysis field ionization mass spectrometryJournal of Plant Nutrition and Soil Science, 1987
- A comparison of four different raw humus types in Norway using chemical degradations and CPMAS 13C NMR spectroscopyGeoderma, 1985
- Use of alkaline soil extracts for 13 C n.m.r. characterization of humic substancesEuropean Journal of Soil Science, 1984
- TOWARDS A DIRECT, NON-DESTRUCTIVE METHOD OF CHARACTERISING SOIL HUMIC SUBSTANCES USING 13C N.M.R.European Journal of Soil Science, 1980
- Selection of nonprotonated carbon resonances in solid-state nuclear magnetic resonanceJournal of the American Chemical Society, 1979
- Characterization of organic material in coal by proton-decoupled 13C nuclear magnetic resonance with magic-angle spinningFuel, 1979
- The [13C]nuclear magnetic resonance spectrum of a methylated humic acidSoil Biology and Biochemistry, 1979
- Proton resonance spectra of humic acids from the solum of a PodzolGeoderma, 1977