Electron paramagnetic resonance of 239Pu3+ and 243Am4+ in CeO2 and of 241Pu3+ in ThO2
- 15 January 1974
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 60 (2), 607-609
- https://doi.org/10.1063/1.1681081
Abstract
The g values of the 5f5 ions Pu3+ and Am4+ in CeO2 cubic symmetry sites have been measured by EPR techniques and found to be 1.333 ± 0.001 and 1.3120 ± 0.0005, respectively. For the case of Pu3+, the cubic crystal field parameters were calculated and compared with those previously obtained for other fluorite‐structure lattices. The EPR spectrum was also observed for 241Pu in ThO2 and the ratio of the magnetic moments 241μI/239μI determined to be 3.52 ± 0.06.Keywords
This publication has 23 references indexed in Scilit:
- Magnetic field enhancement of electrochemiluminescence intensity: Effect in an energy sufficient systemThe Journal of Chemical Physics, 1973
- Zero-field splittings of Gd3+ and Cm3+ in CeO2 and ThO2The Journal of Chemical Physics, 1973
- Effect of Mixing on the Values of the Ground State of Ion and Ion in Cubic Symmetry SitesPhysical Review B, 1972
- Zero-Field Splittings of Cm3+ and Am2+ in Fluorite Type CrystalsThe Journal of Chemical Physics, 1972
- Electron-Nuclear Double Resonance ofin CaPhysical Review B, 1971
- Hyperfine Structure in Trivalent PlutoniumPhysical Review B, 1970
- Electron Paramagnetic Resonance of Pu3+ in Cubic Symmetry Sites in CaF2, SrF2, and BaF2The Journal of Chemical Physics, 1969
- Moment magnetique de Pu 241Physica, 1969
- Single-Crystal Growth of Cerium Dioxide from Lithium Ditungstate SolventJournal of Applied Physics, 1966
- Energy Levels of Pu3+ in Lanthanum TrichlorideThe Journal of Chemical Physics, 1966