Catalytic aziridination of electron-deficient olefins with an N-chloro-N-sodio carbamate and application of this novel method to asymmetric synthesis
- 29 October 2008
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 47,p. 6363-6365
- https://doi.org/10.1039/b812978a
Abstract
A new method for the aziridination of electron-deficient olefins using an N-chloro-N-sodio carbamate is described; the reaction was promoted by phase-transfer catalysis (solid–liquid) and afforded aziridines from α,β-unsaturated ketones, esters, sulfones and amides.Keywords
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