Metal-insulator nanocomposites which act optically like homogeneous conductors
- 1 January 2007
- journal article
- Published by SPIE-Intl Soc Optical Eng in Journal of Nanophotonics
- Vol. 1 (1), 013507-013507-15
- https://doi.org/10.1117/1.2711706
Abstract
Conductor-insulator nanocomposites in which the conductor percolates can have optical responses at longer wavelengths like dense conductors with an effective plasma frequency wp*. This applies at wavelengths where the Bergman spectral function F for permittivity varies sufficiently slowly with wavelength. wp* can be engineered by varying the components, the nanostructure's topology, or the dielectric volume fraction f. The homogenized conductor acts like a dense conductor whose charge carriers have effective mass meff*. Results are presented for wp*(f) and meff*(f) using the Maxwell Garnett (MG) and Bruggemann (BR) models for spheres and aligned ellipsoids. In the BR case meff*(f) at the percolation concentration is singular. Example wp* data for spheres and ellipsoids are given which match predictions. Anisotropy in effective mass is considered, such that effective plasma frequency can depend strongly on polarisation direction of incident light.Keywords
This publication has 13 references indexed in Scilit:
- Homogenized Lorentz–Drude optical response in highly nanoporous conducting gold layers produced by de-alloyingOptics Communications, 2007
- Mesoporous gold sponge as a prototype ‘metamaterial’Physica B: Condensed Matter, 2007
- Resonant Field Enhancements from Metal Nanoparticle ArraysNano Letters, 2003
- Local field distribution in random metal–dielectric films; theory and experimentPhysica B: Condensed Matter, 2003
- Optical properties of thin semicontinuous gold films over a wavelength range of 2.5 to 500 μmPhysical Review B, 1992
- Noble-metal-based transparent infrared reflectors: Experiments and theoretical analyses for very thin gold filmsJournal of Applied Physics, 1986
- The optical properties of cermets from the theory of electrostatic resonancesJournal of Physics C: Solid State Physics, 1982
- Bounds on the complex dielectric constant of a composite materialApplied Physics Letters, 1980
- The dielectric constant of a composite material—A problem in classical physicsPhysics Reports, 1978
- Dielectric constants for mixed mediaJournal of Physics D: Applied Physics, 1977