Palladium-Mediated Ring Opening of Hydroxycyclopropanes
- 30 December 1999
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 2 (2), 147-149
- https://doi.org/10.1021/ol991250r
Abstract
The palladium-mediated ring opening of substituted cyclopropanols has been found to take place predominantly at the less substituted C−C bond. Thus, sequential application of the titanium-mediated cyclopropanation of esters and the palladium-mediated ring opening of the resulting cyclopropanols provides a convenient method for functionalizing monosubstituted olefins.Keywords
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