A new alkyl peroxovanadium catalyst for selective oxidation of nitriles to α-oxo nitriles: A functional mimic of Cyt-P.450
- 10 November 1996
- journal article
- Published by Elsevier BV in Journal of Molecular Catalysis A: Chemical
- Vol. 112 (3), 385-388
- https://doi.org/10.1016/1381-1169(96)00147-1
Abstract
Alkyl peroxovanadium complex catalysed functionalisation of methylene of benzyl cyanides to afford peroxo nitriles or aroyl cyanides selectively depending on the molar quantities of oxidant, tert butyl hydroperoxide (t-BuOOH) used is described for the first time.Keywords
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