Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex
- 23 October 2007
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 2,p. 235-237
- https://doi.org/10.1039/b714216a
Abstract
UVA-induced photodecomposition of a PtIV-diazido complex involves not only reduction to PtII and N2 release, but also O2 evolution and formation of nitrene intermediates, whose trapping with (CH3)2S gives rise to an unusual N,N′-bis(ethyl)sulfurousdiamide ligand in an apparently unprecedented process involving C–C bond formation.Keywords
This publication has 26 references indexed in Scilit:
- Using coordination chemistry to design new medicinesCoordination Chemistry Reviews, 2006
- Insights into the mechanism of action of platinum anticancer drugs from multinuclear NMR spectroscopyProgress in Nuclear Magnetic Resonance Spectroscopy, 2006
- A Photoactivated trans‐Diammine Platinum Complex as Cytotoxic as CisplatinChemistry – A European Journal, 2006
- Light-Activated Destruction of Cancer Cell Nuclei by Platinum Diazide ComplexesCell Chemical Biology, 2006
- Formation of platinated GG cross-links on DNA by photoactivation of a platinum(IV) azide complexJBIC Journal of Biological Inorganic Chemistry, 2003
- Nucleotide Cross‐Linking Induced by Photoreactions of Platinum(IV)–Azide ComplexesAngewandte Chemie-International Edition, 2003
- Photochemical Four-Electron Redox Reaction of Hexaazidoplatinate(IV)Angewandte Chemie-International Edition, 1983
- Photochemical Reductive trans-Elimination from trans-Diacidotetracyanoplatinate(IV) ComplexesZeitschrift für Naturforschung B, 1978
- Photodecomposition of aqueous solutions of barium azideThe Journal of Physical Chemistry, 1968
- Chemical Shifts of 14N in the NMR Spectra of Linear Triatomic Molecules and IonsThe Journal of Chemical Physics, 1966