Gas phase protonolysis reactions
- 1 January 1976
- journal article
- Published by Elsevier BV in Tetrahedron
- Vol. 32 (22), 2689-2692
- https://doi.org/10.1016/0040-4020(76)80107-x
Abstract
Gas phase protonolysis reactions of a wide variety of N-nitrosamines have been studied utilizing methane chemical ionization mass spectrometry (CIMS). N-Nitrosamines are protonated at either the N or O atoms of the N-nitroso triad (NNO) leading to aminium radicals, nitrenium ions, ammonium ions, carbenium ions and various elimination reaction. A structure-CIMS reactivity relationship of N-nitrosamines is presented.Keywords
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