In Situ Generation of Palladium Nanoparticles: A Simple and Highly Active Protocol for Oxygen-Promoted Ligand-Free Suzuki Coupling Reaction of Aryl Chlorides
- 31 August 2007
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 9 (20), 4005-4007
- https://doi.org/10.1021/ol701709q
Abstract
An oxygen-promoted ligand-free Suzuki coupling reaction catalyzed by in situ generated palladium nanoparticles in PEG-400 under aerobic conditions has been demonstrated. The reaction was highly efficient for coupling aryl chlorides with phenylboronic acid in short times under mild conditions.Keywords
This publication has 39 references indexed in Scilit:
- Cyclopropanation of Cyclohexenone by Diazomethane Catalyzed by Palladium Diacetate: Evidence for the Formation of Palladium(0) NanoparticlesOrganometallics, 2007
- Novel bis(oxazole) pincer ligands for catalysis: Application in Suzuki-Miyaura cross coupling reactions under aerobic conditionsJournal of Molecular Catalysis A: Chemical, 2007
- CuI-Catalyzed Suzuki−Miyaura and Sonogashira Cross-Coupling Reactions Using DABCO as LigandThe Journal of Organic Chemistry, 2007
- New Palladium Complexes with S‐ or Se‐Containing Schiff‐Base Ligands as Efficient Catalysts for the Suzuki–Miyaura Cross‐Coupling Reaction of Aryl Bromides with Phenylboronic Acid under Aerobic ConditionsEuropean Journal of Inorganic Chemistry, 2006
- Polyethyleneglycol as scaffold and solvent for reusable CC coupling homogeneous Pd catalystsJournal of Catalysis, 2006
- Captured and Cross-Linked Palladium NanoparticlesJournal of the American Chemical Society, 2006
- Effect of Catalysis on the Stability of Metallic Nanoparticles: Suzuki Reaction Catalyzed by PVP-Palladium NanoparticlesJournal of the American Chemical Society, 2003
- Palladium-Catalyzed Coupling Reactions of Aryl ChloridesAngewandte Chemie-International Edition, 2002
- Carbon−Carbon Bond Formation via Palladium-Catalyzed Reductive Coupling in AirOrganic Letters, 1999
- Palladium-Catalyzed Cross-Coupling Reactions of Organoboron CompoundsChemical Reviews, 1995