Polarization Control of Electron Tunneling into Ferroelectric Surfaces

Abstract
Ferroelectric Patterning with High Fields: Ferroelectric oxides have a net polarization that can switch direction upon application of a sufficiently high electric field. In principle, a ferroelectric thin film should be able to act as a polar switch—tunneling an electron through the film would effectively switch on or off depending on the direction of the polarization. In practice, the length scale needed for a sufficiently small tunneling barrier is nearly the same as the scale at which films no longer support ferroelectricity. Maksymovych et al. (p. 1421 ) now show that the tip of an atomic force microscope can be used to pattern polarization domains in a thin film of lead zirconate titanate in high electric fields similar to those for field emission tips.