Hierarchical silicon nanowires-carbon textiles matrix as a binder-free anode for high-performance advanced lithium-ion batteries
Open Access
- 9 April 2013
- journal article
- research article
- Published by Springer Science and Business Media LLC in Scientific Reports
- Vol. 3 (1), 1622-7
- https://doi.org/10.1038/srep01622
Abstract
Toward the increasing demands of portable energy storage and electric vehicle applications, the widely used graphite anodes with significant drawbacks become more and more unsuitable. Herein, we report a novel scaffold of hierarchical silicon nanowires-carbon textiles anodes fabricated via a facile method. Further, complete lithium-ion batteries based on Si and commercial LiCoO2 materials were assembled to investigate their corresponding across-the-aboard performances, demonstrating their enhanced specific capacity (2950 mAh g−1 at 0.2 C), good repeatability/rate capability (even >900 mAh g−1 at high rate of 5 C), long cycling life, and excellent stability in various external conditions (curvature, temperature, and humidity). Above results light the way to principally replacing graphite anodes with silicon-based electrodes which was confirmed to have better comprehensive performances.Keywords
This publication has 36 references indexed in Scilit:
- An Integrated “Energy Wire” for both Photoelectric Conversion and Energy StorageAngewandte Chemie-International Edition, 2012
- Ultrathin Graphite Foam: A Three-Dimensional Conductive Network for Battery ElectrodesNano Letters, 2012
- Rechargeable Li–O2 batteries with a covalently coupled MnCo2O4–graphene hybrid as an oxygen cathode catalystEnergy & Environmental Science, 2012
- Novel Three‐Dimensional Mesoporous Silicon for High Power Lithium‐Ion Battery Anode MaterialAdvanced Energy Materials, 2011
- Roles of nanosize in lithium reactive nanomaterials for lithium ion batteriesNano Today, 2011
- Deformations in Si−Li Anodes Upon Electrochemical Alloying in Nano-Confined SpaceJournal of the American Chemical Society, 2010
- High-performance lithium battery anodes using silicon nanowiresNature Nanotechnology, 2007
- Porous Co3O4 Nanotubes Derived From Co4(CO)12 Clusters on Carbon Nanotube Templates: A Highly Efficient Material For Li‐Battery ApplicationsAdvanced Materials, 2007
- A multifunctional 3.5 V iron-based phosphate cathode for rechargeable batteriesNature Materials, 2007
- Functional Nanoscale Electronic Devices Assembled Using Silicon Nanowire Building BlocksScience, 2001