Electronic Configuration and Ligand Nature of Five-Coordinate Iron Porphyrin Carbene Complexes: An Experimental Study

Abstract

The five-coordinate iron porphyrin carbene complexes [Fe(TPP) (CCl₂)] (TPP = tetraphenylporphyrin), [Fe(TTP) (CCl₂)] (TTP = tetratolylporphyrin) and [Fe(TFPP) (CPh₂)] (TFPP = tetra(pentafluorophenyl)porphyrin), utilizing two types of carbene ligands (CCl₂ and CPh₂), have been investigated by single crystal X-ray, XANES (X-ray absorption near edge spectroscopy), Mössbauer, NMR and UV–vis spectroscopies. The XANES suggested the iron(II) oxidation state of the complexes. The multitemperature and high magnetic field Mössbauer experiments, which show very large quadrupole splittings (QS, ΔE_Q), determined the S = 0 electronic configuration. More importantly, combined structural and Mössbauer studies, especially the comparison with the low spin iron(II) porphyrin complexes with strong diatomic ligands (CS, CO and CN^–) revealed the covalent bond nature of the carbene ligands. A correlation between the iron isomer shifts (IS, δ) and the axial bond distances is established for the first time for these donor carbon ligands (:C–R).