Novel 3-D Framework Nickel(II) Complex with Azide, Nicotinic Acid, and Nicotinate(1−) as Coligands: Hydrothermal Synthesis, Structure, and Magnetic Properties
- 15 September 2005
- journal article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 44 (21), 7298-7300
- https://doi.org/10.1021/ic051030b
Abstract
The hydrothermal reaction of Ni(NO3)2, NaN3, and nicotinic acid (Hnic) yielded a 3-D supramolecular framework complex, [Ni1.5(N3)(nic)2(Hnic)]n (1) with unusual magnetic properties. In 1, Hnic and nic-1 coexist and show different coordination modes (μ2-Hnic-N,O, μ2-nic-N,O, and μ3-nic-N,O,O bridging NiII ions), and azide groups adopt μ-1,1 (EO) bridging mode linking NiII ions with an unusual Ni−N−Ni angle.Keywords
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