Eu(iii)–cyclen–phen conjugate as a luminescent copper sensor: the formation of mixed polymetallic macrocyclic complexes in water
- 3 March 2004
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 7,p. 782-783
- https://doi.org/10.1039/b316176e
Abstract
The cationic cyclen based Eu(III)–phen conjugated 1·Eu was synthesised as a chemosensor for Cu(II), where the recognition in water at pH 7.4 gave rise to quenching of the Eu(III) luminescence and the formation of tetranuclear polymetallic Cu(II)–Eu(III) macrocyclic complexes in solution where Cu(II) was bound by three 1·Eu conjugates.Keywords
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