Adsorption of gold clusters on metal-supported MgO: Correlation to electron affinity of gold
- 13 August 2007
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 76 (7), 073406
- https://doi.org/10.1103/physrevb.76.073406
Abstract
Adsorption of clusters on a bulk MgO(001) surface and on an ultrathin (3 ML) MgO(001) film supported by Mo metal is investigated via density-functional theory calculations. Comparison of the two substrates unambiguously shows that the gold clusters adsorbed on turn into singly charged cluster anions , . Their structures and internal charging patterns are analogous to singly charged, planar, gas-phase cluster anions . The adsorption energy has prominent size-dependent odd-even oscillations, correlating fully with the known electron affinity of gas-phase Au clusters in this size range.
Keywords
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