Polymer coordination promotes selective CO2reduction by cobalt phthalocyanine
Open Access
- 2 February 2016
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Science
- Vol. 7 (4), 2506-2515
- https://doi.org/10.1039/c5sc04015a
Abstract
We present a study of the mechanistic factors that transform cobalt phthalocyanine from a catalyst that shows modest performance for the electrocatalytic reduction of CO2to CO production into one of the most active and selective molecular catalyst reported in aqueous media when immobilized in a poly-4-vinylpyridine membraneKeywords
Funding Information
- California Energy Commission (500-11-023)
This publication has 91 references indexed in Scilit:
- Structure Sensitivity of the Electrochemical Reduction of Carbon Monoxide on Copper Single CrystalsACS Catalysis, 2013
- New insights into the electrochemical reduction of carbon dioxide on metallic copper surfacesEnergy & Environmental Science, 2012
- Electrocatalytic oxygen reduction and hydrogen evolution reactions on phthalocyanine modified electrodes: Electrochemical, in situ spectroelectrochemical, and in situ electrocolorimetric monitoringElectrochimica Acta, 2011
- Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen ActivationInorganic Chemistry, 2010
- Reduction catalysis by metal complexes confined in a polymer matrixProgress in Polymer Science, 2003
- Modified electrode surfaces for catalytic reduction of carbon dioxideAnalytica Chimica Acta, 1999
- Kinetics and Mechanism of Redox-Coupled, Long-Range Proton Transfer in an Iron−Sulfur Protein. Investigation by Fast-Scan Protein-Film VoltammetryJournal of the American Chemical Society, 1998
- Electrocatalytic reduction of CO2in water by [Re(bpy)(CO)3Br] and [Re(terpy)(CO)3Br] complexes incorporated into coated nafion membrane (bpy = 2,2′-bipyridine; terpy = 2,2′;6′,2″-terpyridine)Journal of the Chemical Society, Chemical Communications, 1993
- Carbon Dioxide Reduction at a Metal Phthalocyanine Catalyzed Carbon ElectrodeJournal of the Electrochemical Society, 1984
- Poly(pyridyl)ruthenium(II) complexes of poly(4-vinylpyridine). Synthesis, characterization and thin-film electrochemistry of a series of bis(bipyridine) metallopolymersInorganic Chemistry, 1982