Expanded graphite as superior anode for sodium-ion batteries
Top Cited Papers
- 4 June 2014
- journal article
- research article
- Published by Springer Science and Business Media LLC in Nature Communications
- Vol. 5 (1), 4033
- https://doi.org/10.1038/ncomms5033
Abstract
Graphite, as the most common anode for commercial Li-ion batteries, has been reported to have a very low capacity when used as a Na-ion battery anode. It is well known that electrochemical insertion of Na+ into graphite is significantly hindered by the insufficient interlayer spacing. Here we report expanded graphite as a Na-ion battery anode. Prepared through a process of oxidation and partial reduction on graphite, expanded graphite has an enlarged interlayer lattice distance of 4.3 Å yet retains an analogous long-range-ordered layered structure to graphite. In situ transmission electron microscopy has demonstrated that the Na-ion can be reversibly inserted into and extracted from expanded graphite. Galvanostatic studies show that expanded graphite can deliver a high reversible capacity of 284 mAh g−1 at a current density of 20 mA g−1, maintain a capacity of 184 mAh g−1 at 100 mA g−1, and retain 73.92% of its capacity after 2,000 cycles.Keywords
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