Mathematical modelling of precious metals catalytic converters for diesel NOx reduction
- 1 March 1999
- journal article
- research article
- Published by SAGE Publications in Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering
- Vol. 213 (3), 279-292
- https://doi.org/10.1243/0954407991526865
Abstract
Precious metal catalysts for NOx reduction in lean diesel engine exhaust conditions are characterized by a narrow temperature range of efficient operation and require high availability of reducing species in significant concentration. Consequently, there exists a large optimization potential in the design and control of lean-NOx catalytic conversion systems. A mathematical model of the transport and chemical phenomena in platinum-based lean-NOx catalysts was formulated, based on the experience with analogous models for gasoline three-way catalysts. A simplified four-reaction scheme is employed, considering the oxidation of CO, H2 and hydrocarbons (HCs), as well as the reaction between NOx and HCs. Results are compared with previously published laboratory and engine data in order to assess the capacity of this approach in representing real-world behaviour of Pt-based lean-NOx catalysts. Initial results illustrate the power and flexibility of the model, which is able to predict the NOx conversion characteristics in model gas tests as well as in full-scale engine tests with reasonable accuracy.Keywords
This publication has 24 references indexed in Scilit:
- The current state of research on automotive lean NOx catalysisApplied Catalysis B: Environment and Energy, 1997
- Catalytic automotive exhaust aftertreatmentProgress in Energy and Combustion Science, 1997
- Catalytic diesel exhaust aftertreatmentApplied Catalysis B: Environment and Energy, 1996
- Selective catalytic reduction of nitric oxide by hydrocarbonsApplied Catalysis B: Environment and Energy, 1996
- Monolithic diesel oxidation catalystsApplied Catalysis B: Environment and Energy, 1996
- Diesel oxidation catalysts for commercial vehicle engines: strategies on their application for controlling particulate emissionsApplied Catalysis B: Environment and Energy, 1996
- Worldwide diesel emission standards, current experiences and future needsApplied Catalysis B: Environment and Energy, 1996
- The relation between deactivation of CuZSM-5 in the selective reduction of NO and dealumination of the zeoliteZeolites, 1993
- Deactivation in Cu-ZSM-5 lean-burn catalystsApplied Catalysis B: Environment and Energy, 1993
- Cu-ZSM-5 zeolite as highly active catalyst for removal of nitrogen monoxide from emission of diesel enginesApplied Catalysis, 1991