Selective aryl coupling via palladacycles: a new route to m-alkylbiphenyls or m-terphenyls

1 January 1998

journal article
research article
Published by Royal Society of Chemistry (RSC) in New Journal of Chemistry

Vol. 22 (8), 759-761
https://doi.org/10.1039/a802846j

Abstract

O-Alkyl- or o-aryl-substituted arylnorbornylpalladium chloride complexes react with aromatic iodides in dimethylformamide (DMF) via palladacycles to give after hydrogenolysis m-alkylbiphenyls or m-terphenyls.

Keywords

PALLADACYCLES
ARYL COUPLING
ALKYLBIPHENYLS
REACT
GIVE
SUBSTITUTED
ARYLNORBORNYLPALLADIUM
DIMETHYLFORMAMIDE

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