Formation of Carbon–Carbon Bonds Using Aminal Radicals
- 29 November 2012
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 14 (23), 6092-6095
- https://doi.org/10.1021/ol3029912
Abstract
Aminal radicals were generated by radical translocation processes. For the first time, it is shown that they participate in carbon–carbon bond forming reactions. Either stannane or silane hydrogen atom donors are suitable for the reaction. More than 30 substrate combinations are reported, and chemical yields are as high as 91%.Keywords
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