Effect of TMEDA on Iron-Catalyzed Coupling Reactions of ArMgX with Alkyl Halides
- 13 April 2009
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 131 (17), 6078-6079
- https://doi.org/10.1021/ja901262g
Abstract
A new reaction mechanism for the iron-catalyzed cross-coupling reaction of ArMgX with alkyl halides using (TMEDA)FeAr2 and (TMEDA)Fe(Ar)Br is proposed on the basis of the isolation and reaction of these organoiron intermediates.Keywords
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