Thermal degradation of CH3NH3PbI3 perovskite into NH3 and CH3I gases observed by coupled thermogravimetry–mass spectrometry analysis
Open Access
- 1 September 2016
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Energy & Environmental Science
- Vol. 9 (11), 3406-3410
- https://doi.org/10.1039/c6ee02016j
Abstract
Thermal gravimetric and differential thermal analysis (TG-DTA) coupled with quadrupole mass spectrometry (MS) and first principles calculations were employed to elucidate the chemical nature of released gases during the thermal decomposition of CH3NH3PbI3.Keywords
Funding Information
- Okinawa Institute of Science and Technology Graduate University
This publication has 21 references indexed in Scilit:
- Light and oxygen induced degradation limits the operational stability of methylammonium lead triiodide perovskite solar cellsEnergy & Environmental Science, 2016
- Organometal halide perovskite solar cells: degradation and stabilityEnergy & Environmental Science, 2015
- Atmospheric effects on the photovoltaic performance of hybrid perovskite solar cellsSolar Energy Materials and Solar Cells, 2015
- The Role of Oxygen in the Degradation of Methylammonium Lead Trihalide Perovskite Photoactive LayersAngewandte Chemie-International Edition, 2015
- Outdoor Performance and Stability under Elevated Temperatures and Long‐Term Light Soaking of Triple‐Layer Mesoporous Perovskite PhotovoltaicsEnergy Technology, 2015
- Temperature- and Component-Dependent Degradation of Perovskite Photovoltaic Materials under Concentrated SunlightThe Journal of Physical Chemistry Letters, 2015
- Bulk crystal growth of hybrid perovskite material CH3NH3PbI3CrystEngComm, 2014
- Properties of CH3NH3PbX3 (X = I, Br, Cl) Powders as Precursors for Organic/Inorganic Solar CellsChemistry of Materials, 2014
- Thermal Behavior of Methylammonium Lead-Trihalide Perovskite Photovoltaic Light HarvestersChemistry of Materials, 2014
- Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applicationsJournal of Materials Chemistry A, 2013