Electrochemical gating of individual single-wall carbon nanotubes observed by electron transport measurements and resonant Raman spectroscopy
- 22 March 2004
- journal article
- research article
- Published by AIP Publishing in Applied Physics Letters
- Vol. 84 (12), 2052-2054
- https://doi.org/10.1063/1.1666997
Abstract
Metal electrodes patterned lithographically on top of individual single-wall carbon nanotubes are used to gate the nanotubes with respect to a reference electrode in an electrolyte drop. The gating is found to have a dramatic effect on both the Raman spectra and electron transport of the nanotubes. Current through metallic nanotubes is found to increase sharply with electrochemical gate voltage, indicating that the Fermi energy reaches valence and conduction band van Hove singularities. Using resonant confocal micro-Raman spectroscopy, we observe a upshift of the tangential mode vibrational frequency, as well as a 90% decrease in intensity, by applying 1 V between an individual nanotube and a silver reference electrode in a dilute solution. The mechanisms for the shifts of the Raman mode frequencies are discussed on the basis of changes in the lattice constant of heavily charged nanotubes.
Keywords
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