Self‐Enhanced Electrochemiluminescence of an Iridium(III) Complex: Mechanistic Insight
- 4 October 2012
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 51 (44), 11079-11082
- https://doi.org/10.1002/anie.201206074
Abstract
Improved luminophore: The electrochemiluminescence (ECL) of an iridium complex self‐enhanced up to 16 times is reported. Three excited states were observed in the emission spectra (see picture). The ECL efficiency of this complex is the highest reported for an iridium complex.Keywords
This publication has 36 references indexed in Scilit:
- Synthesis, Structure, Electrochemistry, and Electrochemiluminescence of ThienyltriazolesThe Journal of Organic Chemistry, 2012
- Electrochemistry and electrogenerated chemiluminescence of thiophene and fluorene oligomers. Benzoyl peroxide as a coreactant for oligomerization of thiophene dimersChemical Science, 2012
- Enhanced Luminescent Iridium(III) Complexes Bearing Aryltriazole Cyclometallated LigandsInorganic Chemistry, 2011
- Electrogenerated chemiluminescence of triazole-modified deoxycytidine analogues in N,N-dimethylformamidePhysical Chemistry Chemical Physics, 2011
- Complex Iridium(III) Salts: Luminescent Porous Crystalline MaterialsAngewandte Chemie, 2010
- Efficient and Stable Blue Electrogenerated Chemiluminescence of Fluorene‐Substituted Aromatic HydrocarbonsAngewandte Chemie-International Edition, 2009
- Electrogenerated Chemiluminescence. 80. C-Reactive Protein Determination at High Amplification with [Ru(bpy)3]2+-Containing MicrospheresAnalytical Chemistry, 2004
- Electrogenerated Chemiluminescence. 77. DNA Hybridization Detection at High Amplification with [Ru(bpy)3]2+-Containing MicrospheresAnalytical Chemistry, 2004
- Electrogenerated Chemiluminescence. 70. The Application of ECL to Determine Electrode Potentials of Tri-n-propylamine, Its Radical Cation, and Intermediate Free Radical in MeCN/Benzene SolutionsThe Journal of Physical Chemistry A, 2003
- Electrogenerated Chemiluminescence. 66. The Role of Direct Coreactant Oxidation in the Ruthenium Tris(2,2‘)bipyridyl/Tripropylamine System and the Effect of Halide Ions on the Emission IntensityAnalytical Chemistry, 2000