Highly efficient blue OLED based on 9-anthracene-spirobenzofluorene derivatives as host materials
- 6 October 2010
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 20 (47), 10735-10746
- https://doi.org/10.1039/c0jm00593b
Abstract
A novel spiro[benzo[c]fluorene-7,9′-fluorene](SBFF)-based blue host material, 9-(10-phenylanthracene-9-yl)SBFF (BH-9PA), 9-(10-(naphthalene-1-yl)anthracene-9-yl)SBFF (BH-9NA) and 9-(10-(4-(naphthalene-1-yl)phenyl)anthracene-9-yl)SBFF (BH-9NPA) were successfully prepared by reacting 9-bromo-SBFF (2) with 10-phenylanthracene-9-yl boronic acid, 10-(naphthalene-1-yl)anthracene-9-yl boronic acid and 10-(4-(naphthalene-1-yl)phenyl)anthracene-9-yl boronic acid through the Suzuki reaction, respectively. Bis[4-(di-p-N,N-diphenylamino)styryl]stilbene (DSA-Ph) and N,N-diphenyl-N′,N′-dim-tolyl-SBFF-5,9-diamine (BD-6MDPA) were used as dopant materials. Blue OLEDs with the configuration ITO/DNTPD/NPB/host : 5% dopant/Alq3/Al-LiF were prepared from the three host materials doped with DSA-Ph and BD-6MDPA dopants and the device composed of BH-9PA doped with DSA-Ph and BD-6MDPA showed blue EL spectra at 468 and 464 nm at 7 V and luminance efficiencies of 7.03 and 6.60 cd A−1, respectively.Keywords
This publication has 33 references indexed in Scilit:
- Thermally Stable Hole-Transporting Materials Based upon a Fluorene CoreAdvanced Functional Materials, 2002
- Spiro-Linked Ter-, Penta-, and Heptafluorenes as Novel Amorphous Materials for Blue Light EmissionChemistry of Materials, 2002
- 9,9-Bis{4-[di-(p-biphenyl)aminophenyl]}fluorene: a high Tg and efficient hole-transporting material for electroluminescent devicesSynthetic Metals, 2002
- Characterization of Hole Transport in a New Class of Spiro-Linked Oligotriphenylamine CompoundsAdvanced Materials, 2000
- Hole Transporting Materials with High Glass Transition Temperatures for Use in Organic Light-Emitting DevicesAdvanced Materials, 1998
- A Novel Class of π-Electron Dendrimers for Thermally and Morphologically Stable Amorphous Molecular MaterialsAdvanced Materials, 1998
- Spiro linked compounds for use as active materials in organic light emitting diodesMacromolecular Symposia, 1998
- Low molecular organic glasses for blue electroluminescenceSynthetic Metals, 1997
- Convergent Synthetic Routes to Orthogonally Fused Conjugated Oligomers Directed toward Molecular Scale Electronic Device ApplicationsThe Journal of Organic Chemistry, 1996
- Development of the Colle-Salvetti correlation-energy formula into a functional of the electron densityPhysical Review B, 1988