Bonding and structure of water molecules in solid hydrates. Correlation of spectroscopic and structural data
- 1 January 1988
- book chapter
- conference paper
- Published by Springer Science and Business Media LLC
Abstract
Solid hydrate research of the last fifteen years is critically evaluated with regard to bonding and structure of water molecules. This review focusses on new results of structure determination and infrared and Raman studies in terms of hydrogen bonding and other intermolecular bonding interactions, distortion and disorder of water molecules, intermolecular and intramolecular coupling and anharmonicity of water bands, isotopic effects, and phase transitions. The techniques used for structure determination and spectroscopic measurements of solid hydrates are discussed.Keywords
This publication has 100 references indexed in Scilit:
- Influence of alkali cations on the infrared spectra of water molecules in aprotic solventsThe Journal of Physical Chemistry, 1986
- Degradation studies on nickel nitrate hexahydrate. Part 3. Raman and infrared analysisThermochimica Acta, 1986
- Single crystal Raman studies on magnesium sulphite trihydrate, MgSO3·3H2O and MgSO3·3(H, D)2OJournal of Raman Spectroscopy, 1984
- The infrared and Raman spectra of potassium azidopentacyanocobaltate(III) dihydrate: K3[Co(CN)5N3]·2H2OJournal of Chemical Crystallography, 1983
- Activité Raman et Infrarouge des Cristaux Piezo Electriques BeSO4·4 H2O et BeSO4·4 D2O. 1-Vibrations Principales et StructureJournal of Raman Spectroscopy, 1982
- Hydrates of barium hydroxide. Preparation, thermal decomposition and X-ray dataThermochimica Acta, 1981
- The deuterium isotope effect in enthalpy change on the thermal dehydration of calcium oxalate monohydrateThermochimica Acta, 1980
- Gitterschwingungsspektren. XIX-infrarot- und Ramanspektren von BaBr2·2H2O und BaBr2·2D2OJournal of Raman Spectroscopy, 1978
- Low-Frequency Motions of H2O Molecules in CrystalsThe Journal of Chemical Physics, 1964
- Structure of the Water Molecule in Solid Hydrated CompoundsThe Journal of Chemical Physics, 1961