Verification of Contaminant Sorption by Soil–Bentonite Barrier Materials Using Scanning Electron Microscopy/Energy Dispersive X-Ray Spectrometry
- 1 August 2004
- journal article
- Published by American Society of Civil Engineers (ASCE) in Journal of Environmental Engineering
- Vol. 130 (8), 910-917
- https://doi.org/10.1061/(asce)0733-9372(2004)130:8(910)
Abstract
The performance of a soil–bentonite barrier material as a sorbent for heavy metals was investigated in the laboratory using an influent containing 20 mg/L of at a pH of 5. The target parameters were the hydraulic conductivity of the soil–bentonite mix and the difference between concentrations in the influent and effluent. A hydraulic conductivity of was achieved, the mixture was found to meet common regulatory specifications for hazardous waste containment. After four pore volumes of flow through specimens placed in a column, no was detected in the effluent. Sorption was verified through acid extraction and identification of on barrier sample cross sections using microanalysis of specimen slices with a scanning electron microscope and the associated energy dispersive x-ray spectrometry. Energy dispersive x-ray spectrometry spectra indicated that the partitioned selectively to the bentonite fraction of the mix. The results confirm the ability of this mixture of soil–bentonite to function as an effective barrier for aqueous solution. This method of microanalysis appears to have promise as an effective tool for assessing relative affinity of contaminants for specific mineralogical constituents of a barrier mixture and may have applications in sorption performance assessments of other multicomponent barrier systems. If each barrier material is tested separately, the effects of the texture of the mix on sorption and hydraulic characteristics of the mix cannot be effectively assessed.
Keywords
This publication has 25 references indexed in Scilit:
- Pore Fluid Properties and Compressibility of KaoliniteJournal of Geotechnical and Geoenvironmental Engineering, 2000
- Bonemeal Additions as a Remediation Treatment for Metal Contaminated SoilEnvironmental Science & Technology, 2000
- Monitoring of internal failure evolution in soils using computerization X-ray tomographyEngineering Geology, 1999
- Geochemistry of a Permeable Reactive Barrier for Metals and Acid Mine DrainageEnvironmental Science & Technology, 1999
- Immobilization of Heavy Metals by Polynuclear Aluminium and Montmorillonite CompoundsEnvironmental Science & Technology, 1997
- Laboratory Sorption and Hydraulic Conductivity Tests: Evaluation of Modified-Clay MaterialsWaste Management & Research: The Journal for a Sustainable Circular Economy, 1996
- Processes of Formation and Distribution of Pb-, Zn-, Cd-, and Cu-Bearing Minerals in the Tyne Basin, Northeast England: Implications for Metal-Contaminated River SystemsEnvironmental Science & Technology, 1995
- State-of-the-Art: Laboratory Hydraulic Conductivity Tests for Saturated SoilsPublished by ASTM International ,1994
- Hydraulic Conductivity of Vertical Cutoff WallsPublished by ASTM International ,1994
- Surface area of claysLangmuir, 1990