Useful Application of Acidic Ionic Liquids as Solvents in Baeyer–Villiger Oxidation with Hydrogen Peroxide for the Synthesis of Lactones
- 27 June 2008
- journal article
- research article
- Published by Informa UK Limited in Synthetic Communications
- Vol. 38 (14), 2385-2391
- https://doi.org/10.1080/00397910802138926
Abstract
Cyclic ketones have been efficiently oxidized with hydrogen peroxide using acidic ionic liquids (ILs) as solvents. This is a new method for the synthesis of lactones with high yields that does not utilize any additional catalysts and enables ILs to be recycled.Keywords
This publication has 12 references indexed in Scilit:
- Addendum to “CH3ReO3/H2O2 in room temperature ionic liquids: an homogeneous recyclable catalytic system for the Baeyer–Villiger reaction”: [Tetrahedron Lett. 44 (2003) 8991]Tetrahedron Letters, 2005
- The Pt(ii)-catalyzed Baeyer–Villiger oxidation of cyclohexanone with H2O2 in ionic liquidsGreen Chemistry, 2005
- The first utilization of acidic ionic liquid for preparation of tetraarylporphyrinsChemical Communications, 2004
- Sn-β molecular sieve catalysed Baeyer–Villiger oxidation in ionic liquid at room temperatureGreen Chemistry, 2004
- Baeyer–Villiger Oxidations in Ionic Liquids. A Facile Conversion of Ketones to Esters and LactonesChemistry Letters, 2004
- Brønsted acidic ionic liquid 1-methylimidazolium tetrafluoroborate: a green catalyst and recyclable medium for esterificationGreen Chemistry, 2002
- Catalysed esterifications in room temperature ionic liquids with acidic counteranion as recyclable reaction mediaCatalysis Communications, 2002
- Hydrogensulfate and tetrakis(hydrogensulfato)borate ionic liquids: synthesis and catalytic application in highly Brønsted-acidic systems for Friedel–Crafts alkylationGreen Chemistry, 2002
- Room-Temperature Ionic Liquids. Solvents for Synthesis and CatalysisChemical Reviews, 1999
- Transition Metal Catalysis in the Baeyer-Villiger Oxidation of KetonesAngewandte Chemie-International Edition, 1998