Conducting metallophthalocyanine 2D covalent organic frameworks: the role of central metals in controlling π-electronic functions
- 19 July 2012
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 48 (71), 8952-8954
- https://doi.org/10.1039/c2cc33929c
Abstract
Phthalocyanine covalent organic frameworks with different central metals are synthesized, and the AA-stacking structure of the 2D polymer sheets results in periodic phthalocyanine π-columns. The central metals control the π-electronic functions, including the improvement of light absorbance, the ease of carrier transport, and the photocurrent gain.Keywords
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