Proposed Structure for Calcium Silicate Hydrate Gel

Abstract

Calcium silicate hydrate gel is a very poorly crystalline material that is the main product of reaction of portland cement with water. Evidence is presented for a disordered layer structure, in which most of the layers are structurally imperfect ones of jennite (Ca₉Si₆O₃₂H₂₂), and others are similarly related to 1.4-nm tobermorite (Ca₅Si₆O₂₆H₁₈), both structures being modified by omission of many of their silicate tetrahedra. The evidence comprises conditions of formation, silicate anion type, Ca/Si ratio, H₂O/Ca ratios and densities for various drying conditions, thermogravimetric curve, X-ray powder and selected-area electron diffraction patterns, and results of analytical electron microfcopy.