Visible‐Light‐Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives
Top Cited Papers
- 28 October 2015
- journal article
- review article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 54 (52), 15632-15641
- https://doi.org/10.1002/anie.201505731
Abstract
Visible-light-induced radical decarboxylative functionalization of carboxylic acids and their derivatives has recently received considerable attention as a novel and efficient method to create CC and CX bonds. Generally, this visible-light-promoted decarboxylation process can smoothly occur under mild reaction conditions with a broad range of substrates and an excellent functional-group tolerance. The radical species formed from the decarboxylation step can participate in not only single photocatalytic transformations, but also dual-catalytic cross-coupling reactions by combining photoredox catalysis with other catalytic processes. Recent advances in this research area are discussed herein.Keywords
Funding Information
- National Science Foundation of China (21232003, 21202053, 21272087, 21472057)
- National Basic Research Program of China (2011CB808603)
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