Siloxides as Supporting Ligands in Uranium(III)-Mediated Small-Molecule Activation
- 5 November 2012
- journal article
- zuschrift
- Published by Wiley in Angewandte Chemie
- Vol. 124 (49), 12446-12450
- https://doi.org/10.1002/ange.201206955
Abstract
Siloxide unterstützen die Reduktion kleiner Moleküle durch Uran-Komplexe. Die Behandlung von [U{N(SiMe3)2}3] mit HOSi(OtBu)3 (3 Äquiv.) liefert den neuartigen homoleptischen Uran(III)-Siloxid-Komplex 1, der als Zwei-Elektronen-Reduktionsmittel für CS2 und CO2 (siehe Schema) wirkt. Komplex 1 reduziert außerdem Toluol und bildet einen invertierten Diuran-Sandwichkomplex.Keywords
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