CuO Nanoparticles Catalyzed C−N, C−O, and C−S Cross-Coupling Reactions: Scope and Mechanism
Top Cited Papers
- 27 January 2009
- journal article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 74 (5), 1971-1976
- https://doi.org/10.1021/jo8024253
Abstract
CuO nanoparticles have been studied for C−N, C−O, and C−S bond formations via cross-coupling reactions of nitrogen, oxygen, and sulfur nucleophiles with aryl halides. Amides, amines, imidazoles, phenols, alcohols and thiols undergo reactions with aryl iodides in the presence of a base such as KOH, Cs2CO3, and K2CO3 at moderate temperature. The procedure is simple, general, ligand-free, and efficient to afford the cross-coupled products in high yield.Keywords
This publication has 100 references indexed in Scilit:
- Pd-Catalyzed Amidations of Aryl Chlorides Using Monodentate Biaryl Phosphine Ligands: A Kinetic, Computational, and Synthetic InvestigationJournal of the American Chemical Society, 2007
- Effect of Substitution of [Pd(PPh3)4] by Related Compounds as Catalysts in Reactions of Organic SynthesesCatalysis Letters, 2006
- Captured and Cross-Linked Palladium NanoparticlesJournal of the American Chemical Society, 2006
- Mild Conditions for Copper‐Catalyzed Coupling Reaction of Phenols and Aryl Iodides and BromidesAdvanced Synthesis & Catalysis, 2006
- The Role of Pd Nanoparticles in Ionic Liquid in the Heck ReactionJournal of the American Chemical Society, 2005
- Catalysts for Cross‐Coupling Reactions with Non‐activated Alkyl HalidesAngewandte Chemie, 2005
- Hydroxyapatite-Supported Palladium Nanoclusters: A Highly Active Heterogeneous Catalyst for Selective Oxidation of Alcohols by Use of Molecular OxygenJournal of the American Chemical Society, 2004
- Aromatic Aminations by Heterogeneous Ni0/C CatalysisAngewandte Chemie, 2000
- Transition Metal Catalyzed Synthesis of Arylamines and Aryl Ethers from Aryl Halides and Triflates: Scope and MechanismAngewandte Chemie-International Edition, 1998
- A General Copper-Catalyzed Synthesis of Diaryl EthersJournal of the American Chemical Society, 1997