From acyclic to cyclic α-amino vinylphosphonates by using ring-closing metathesis
- 5 December 2016
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Organic & Biomolecular Chemistry
- Vol. 15 (2), 387-395
- https://doi.org/10.1039/C6OB02548J
Abstract
Acyclic α-amino vinylphosphonates were alkylated through the Mitsunobu reaction then diolefinic compounds hence formed were subjected to RCM. Studies on the scope and limitations of RCM with these sterically hindered α-amino vinylphosphonates are detailed.Keywords
This publication has 35 references indexed in Scilit:
- Impact on Hydrogenation Catalytic Cycle of the R Groups’ Cyclic Feature in “R-SMS-Phos”Organic Letters, 2010
- Heavyweight “R-SMS-Phos” Ligands in the Olefins’ Hydrogenation ArenaOrganic Letters, 2010
- Asymmetric Hydrogenation of Enamides, α-Enol and α-Enamido Ester Phosphonates Catalyzed by IndolPhos-Rh ComplexesThe Journal of Organic Chemistry, 2009
- Chiral 1,2,3,4‐Tetrahydro‐1‐naphthylamine‐Derived Phosphine‐Phosphoramidite Ligand (THNAPhos): Application in Highly Enantioselective Hydrogenations of Functionalized CC BondsAdvanced Synthesis & Catalysis, 2008
- Readily Available Chiral Phosphine−Aminophosphine Ligands for Highly Efficient Rh-Catalyzed Asymmetric Hydrogenation of α-Enol Ester Phosphonates and α-Enamido PhosphonatesThe Journal of Organic Chemistry, 2008
- Prevention of Undesirable Isomerization during Olefin MetathesisJournal of the American Chemical Society, 2005
- Carbapenem-based prodrugs. Design, synthesis, and biological evaluation of carbapenemsEuropean Journal of Medicinal Chemistry, 2005
- Enantioselective Synthesis of α-Hydroxy and α-Amino Phosphonates via Catalytic Asymmetric HydrogenationOrganic Letters, 1999
- Catalytic stereoselective synthesis of α-Amino phosphonic acid derivatives by asymmetric hydrogenationSynthetic Communications, 1996
- Synthesis of Carboxylic Acids via PO‐Activated Olefination of Tetraethyl Dimethylamino‐methylenediphosphonateAngewandte Chemie-International Edition, 1968