Allylation of N-heterocycles with allylic alcohols employing self-assembling palladium phosphane catalysts
- 19 March 2008
- journal article
- research article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 10 (6), 1207-1210
- https://doi.org/10.1021/ol800073v
Abstract
The first palladium catalyst system that allows the direct allylation of indoles with allylic alcohols as substrates with water being the only byproduct is presented. The application of self-assembing ligands based on complementary hydrogen bonding was the key to success.Keywords
This publication has 30 references indexed in Scilit:
- Design and Preparation of a Chiral Ligand Based on a Pseudorotaxane Skeleton: Application to Rhodium-Catalyzed Enantioselective Hydrogenation of EnamidesJournal of the American Chemical Society, 2007
- Catalysis by Design: Wide‐Bite‐Angle Diphosphines by Assembly of Ditopic Ligands for Selective Rhodium‐Catalyzed HydroformylationAngewandte Chemie-International Edition, 2007
- Self-Assembled Bidentate Ligands for Ruthenium-Catalyzed Hydration of NitrilesOrganometallics, 2007
- Palladium-Catalyzed Enantioselective C-3 Allylation of 3-Substituted-1H-Indoles Using TrialkylboranesJournal of the American Chemical Society, 2006
- Self‐Assembled Bidentate Ligands for Ru‐Catalyzed anti‐Markovnikov Hydration of Terminal AlkynesAngewandte Chemie, 2006
- Self‐Assembled Bidentate Ligands for Ru‐Catalyzed anti‐Markovnikov Hydration of Terminal AlkynesAngewandte Chemie-International Edition, 2006
- Dramatic Rate Acceleration by a Diphenyl-2-pyridylphosphine Ligand in the Hydration of Nitriles Catalyzed by Ru(acac)2 ComplexesOrganometallics, 2005
- Supramolecular Approaches to Generate Libraries of Chelating Bidentate Ligands for Homogeneous CatalysisAngewandte Chemie-International Edition, 2005
- Pd-catalyzed C3-selective allylation of indoles with allyl alcohols promoted by triethylboraneJournal of the American Chemical Society, 2005
- Supraphos: A Supramolecular Strategy To Prepare Bidentate LigandsJournal of the American Chemical Society, 2004