Abstract
For the first time a ground based technique, i.e. incoherent scatter observation of the mesospheric spectra has been utilized in identifying the ‘transition height’ of simple molecular ions to complex cluster ions around 80–90 km in the D-region. This transition height also matches with the electron density ledge. A substantial diurnal variation of this height is observed. The transition height varies by about 10km during the course of a day, the lowest being 80 km, near noon. There is also a strong likelihood that both the neutral temperature and effective positive ion mass vary during the course of a day.

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