A Radically Configurable Six-State Compound
- 25 January 2013
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 339 (6118), 429-433
- https://doi.org/10.1126/science.1228429
Abstract
Radically Organic: Metals such as manganese are relatively stable over a wide range of oxidation states. In contrast, purely organic compounds are rarely susceptible to incremental addition or removal of electrons without accompanying fragmentation or coupling reactions. Barnes et al. (p. 429 ; see the Perspective by Benniston ) report a catenane (a compound comprising interlocked rings) in which the topological structure stabilizes six different states that successively differ by the presence or absence of one or two electrons in the framework. The hepta-oxidized state proved remarkably resilient to oxygen exposure.Keywords
This publication has 41 references indexed in Scilit:
- Organic tailored batteries materials using stable open-shell molecules with degenerate frontier orbitalsNature Materials, 2011
- Playing with organic radicals as building blocks for functional molecular materialsChemical Society Reviews, 2011
- Radically enhanced molecular recognitionNature Chemistry, 2009
- A 160-kilobit molecular electronic memory patterned at 1011 bits per square centimetreNature, 2007
- Magneto-Opto-Electronic Bistability in a Phenalenyl-Based Neutral RadicalScience, 2002
- Chemical Redox Agents for Organometallic ChemistryChemical Reviews, 1996
- Molecular Meccano. 4. The Self-Assembly of [2]Catenanes Incorporating Photoactive .pi.-Extended SystemsJournal of the American Chemical Society, 1995
- A ferromagnetic transition at 1.48 K in an organic nitroxideNature, 1993
- Pyridinyl diradical .pi.-mer. Magnesium iodide complexesJournal of the American Chemical Society, 1971
- Stable radical ionsPure and Applied Chemistry, 1967