Jahn–Teller distortions of six-coordinate CuII compounds: cis or trans?
- 9 June 2009
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 28,p. 4242-4244
- https://doi.org/10.1039/b903867a
Abstract
Unlike their octahedral analogues, copper(II) compounds with trigonal prismatic stereochemistry undergo an elongation of two bonds in cis positions due to a Jahn–Teller effect, a behavior that can also occur in slightly twisted octahedra.Keywords
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