Specific volume measurements of Cu, Mo, Pd, and Ag and calibration of the ruby R1 fluorescence pressure gauge from 0.06 to 1 Mbar

Abstract
The wavelength shift with pressure of the ruby R1 fluorescence line (Δλ) has been calibrated in the diamond‐window pressure cell from 0.06 to 1 Mbar. This was done by simultaneously making specific volume measurements of four metals (Cu, Mo, Ag, and Pd) and referring these results to isothermal equations of state derived from shock‐wave experiments. The result is P (Mbar) = (19.04/5) {[(λ0+Δλ)/λ0]5−1}, where λ0 is the wavelength measured at 1 bar.