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Photolysis of Acyl Group IV Metalloids: the Formation of Silyl Radicals
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Photolysis of Acyl Group IV Metalloids: the Formation of Silyl Radicals
Photolysis of Acyl Group IV Metalloids: the Formation of Silyl Radicals
AB
A. G. Brook
A. G. Brook
PD
P. J. Dillon
P. J. Dillon
RP
R. Pearce
R. Pearce
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1 January 1971
journal article
Published by
Canadian Science Publishing
in
Canadian Journal of Chemistry
Vol. 49
(1)
,
133-135
https://doi.org/10.1139/v71-020
Abstract
The photolyses of several acylsilanes and one acylgermane in carbon tetrachloride have been shown to involve Norrish Type I cleavage of the metalloid-acyl bond to give metalloidal radicals. These radicals readily abstract chlorine from the solvent.
Keywords
CHLORINE
RADICALS
CLEAVAGE
METALLOIDS
GIVE
READILY
PHOTOLYSES
ACYLGERMANE
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Cited by 23 articles