Impact of Film Stoichiometry on the Ionization Energy and Electronic Structure of CH3NH3PbI3 Perovskites
- 25 November 2015
- journal article
- research article
- Published by Wiley in Advanced Materials
- Vol. 28 (3), 553-559
- https://doi.org/10.1002/adma.201503406
Abstract
T he electronic structure of a large sample set of CH3NH3PbI3-based perovskites is studied. Combined investigations by UV/X-ray photoelectron spectroscopy and X-ray diffraction reveal that interstitials present in the film lead to changes in the occupied density of states close to the valence band, which in turn influences the performance of solar cells. Changes in elemental composition tune the ionization energy of the perovskite film by almost 1 eV without introducing significant amounts of gap states.This publication has 32 references indexed in Scilit:
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