A Substituted Hypersensitive Radical Probe for Enzyme-Catalyzed Hydroxylations: Synthesis of Racemic and Enantiomerically Enriched Forms and Application in a Cytochrome P450-Catalyzed Oxidation
- 1 December 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 62 (26), 9114-9122
- https://doi.org/10.1021/jo9712097
Abstract
No abstract availableKeywords
This publication has 18 references indexed in Scilit:
- Heme-Containing OxygenasesChemical Reviews, 1996
- Cytochrome P450-Catalyzed Hydroxylation of Hydrocarbons: Kinetic Deuterium Isotope Effects for the Hydroxylation of an Ultrafast Radical ClockBiochemistry, 1994
- Cytochrome P450 hydroxylation of hydrocarbons: Variation in the rate of oxygen rebound using cyclopropyl radical clocks including two new ultrafast probesBiochemistry, 1993
- Vases and kites as cavitandsJournal of the American Chemical Society, 1991
- A novel route to cyclopropyl ketones, aldehydes, and carboxylic acids.Tetrahedron Letters, 1991
- Mechanisms of cytochrome P‐450 catalysisThe FASEB Journal, 1990
- Timing of the radical recombination step in cytochrome P-450 catalysis with ring-strained probesJournal of the American Chemical Society, 1987
- Transfer of ethylidene from .eta.5-C5H5(CO)2Fe:CHMe+ to para-substituted styrenes. Loss of stereochemistry about the C.alpha.-C.beta. double bond of cis-.beta.-deuterio-p-methoxystyreneOrganometallics, 1984
- Regiospecific synthesis of islandicin methyl etherThe Journal of Organic Chemistry, 1980
- Magnetic resonance spectroscopy on carbon-13 labeled uracil in transfer ribonucleic acidJournal of the American Chemical Society, 1976