Rapid Production of Metal−Organic Frameworks via Microwave-Assisted Solvothermal Synthesis
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- 1 September 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (38), 12394-12395
- https://doi.org/10.1021/ja0635231
Abstract
This paper describes a very rapid technique for the production of metal−organic frameworks (MOF). The method uses a conventional microwave to nucleate crystal growth. A MOF synthesis that used to take hours or days can now be completed in 30 s to 2 min. The yield goes from ∼30% to over 90%. Novel MOFs can be made, since the growth process is no longer dependent on the walls or dust particles for nucleation. Particle sizes have a narrower distribution. Further, the particle size can be controlled by varying the precursor concentration.Keywords
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