Photodegradation of toluene over TiO2–xNx under visible light irradiation
- 27 January 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Physical Chemistry Chemical Physics
- Vol. 8 (9), 1116-1121
- https://doi.org/10.1039/b517653k
Abstract
We report the photooxidation of toluene over nitrogen doped TiO2 (TiO2−xNx) under visible light irradiation. The photocatalytic oxidation of toluene in air over TiO2−xNx powders was studied using diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS), gas chromatography (GC), ion chromatography (IC), and gas chromatography mass spectrometry (GC-MS), focusing on the photocatalytic decomposition processes of toluene. Results obtained indicate that toluene, weakly adsorbed on the catalyst surface, is initially photooxidized to benzaldehyde which adsorbs onto the TiO2−xNx surface more strongly, leading to the formation of ring-opening products such as carboxylic acids and aldehydes. No gaseous intermediates were detected during the photooxidation. Major intermediates adsorbed at the catalyst surface were oxalic acid, (COOH)2, acetic acid, CH3COOH, formic acid, HCOOH, and pyruvic acid, CH3COCOOH, whereas more complicated carboxylic species, including propionic acid, CH3CH2COOH, isovaleric acid, (CH3)2CHCH2COOH, and succinic acid, (CH2COOH)2, were also found in the early stage of the photooxidation. These intermediate products were gradually photodegraded to CO2 and H2O under visible light irradiation.Keywords
This publication has 51 references indexed in Scilit:
- Daylight Photocatalysis by Carbon‐Modified Titanium DioxideAngewandte Chemie-International Edition, 2003
- Fourier Transform Infrared Study of the Performance of Nanostructured TiO2 Particles for the Photocatalytic Oxidation of Gaseous TolueneJournal of Catalysis, 2001
- Photocatalytic Oxidation of Toluene on Nanoscale TiO2 Catalysts: Studies of Deactivation and RegenerationJournal of Catalysis, 2000
- Trichloroethylene-Promoted Photocatalytic Oxidation of Air ContaminantsJournal of Catalysis, 1997
- Catalyst Deactivation in Gas–Solid PhotocatalysisJournal of Catalysis, 1996
- Heterogeneous Photocatalytic Oxidation of Trichloroethylene and Toluene Mixtures in Air: Kinetic Promotion and Inhibition, Time-Dependent Catalyst ActivityJournal of Catalysis, 1996
- Heterogeneous photocatalytic oxidation of gas-phase organics for air purification: Acetone, 1-butanol, butyraldehyde, formaldehyde, and m-xylene oxidationJournal of Catalysis, 1992
- Photocatalytic Deodorization on TiO2 Coated Honeycomb CeramicsDenki Kagaku oyobi Kogyo Butsuri Kagaku, 1991
- Rate constants for the gas‐phase reactions of the OH radical with a series of aromatic hydrocarbons at 296 ± 2 KInternational Journal of Chemical Kinetics, 1989
- Toluene oxidation on u.v.-irradiated titanium dioxide with and without O2, NO2 OR H2O at ambient temperatureAtmospheric Environment (1967), 1986