Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
- 23 September 2009
- journal article
- research article
- Published by Springer Science and Business Media LLC in Nature Chemistry
- Vol. 1 (7), 552-556
- https://doi.org/10.1038/nchem.367
Abstract
The widespread use of low-temperature polymer electrolyte membrane fuel cells for mobile applications will require significant reductions in the amount of expensive Pt contained within their cathodes, which drive the oxygen reduction reaction (ORR). Although progress has been made in this respect, further reductions through the development of more active and stable electrocatalysts are still necessary. Here we describe a new set of ORR electrocatalysts consisting of Pd or Pt alloyed with early transition metals such as Sc or Y. They were identified using density functional theory calculations as being the most stable Pt- and Pd-based binary alloys with ORR activity likely to be better than Pt. Electrochemical measurements show that the activity of polycrystalline Pt3Sc and Pt3Y electrodes is enhanced relative to pure Pt by a factor of 1.5–1.8 and 6–10, respectively, in the range 0.9–0.87 V.Keywords
This publication has 36 references indexed in Scilit:
- Adsorbate‐Induced Surface Segregation for Core–Shell NanocatalystsAngewandte Chemie-International Edition, 2009
- Origin of Oxygen Reduction Reaction Activity on “Pt3Co” Nanoparticles: Atomically Resolved Chemical Compositions and StructuresThe Journal of Physical Chemistry C, 2008
- Increased Oxygen Coverage at Pt−Fe Alloy Cathode for the Enhanced Oxygen Reduction Reaction Studied by EC−XPSThe Journal of Physical Chemistry C, 2008
- Theoretical Trends in Particle Size Effects for the Oxygen Reduction ReactionZeitschrift für Physikalische Chemie, 2007
- Electrocatalysis on Bimetallic Surfaces: Modifying Catalytic Reactivity for Oxygen Reduction by Voltammetric Surface DealloyingJournal of the American Chemical Society, 2007
- Improved Oxygen Reduction Activity on Pt 3 Ni(111) via Increased Surface Site AvailabilityScience, 2007
- Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic StructureAngewandte Chemie, 2006
- Activity benchmarks and requirements for Pt, Pt-alloy, and non-Pt oxygen reduction catalysts for PEMFCsApplied Catalysis B: Environment and Energy, 2005
- Oxygen reduction on high surface area Pt-based alloy catalysts in comparison to well defined smooth bulk alloy electrodesElectrochimica Acta, 2002
- Oxygen Reduction on Carbon-Supported Pt−Ni and Pt−Co Alloy CatalystsThe Journal of Physical Chemistry B, 2002