Biomimetic Catalysis of a Porous Iron-Based Metal–Metalloporphyrin Framework
- 20 November 2012
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 51 (23), 12600-12602
- https://doi.org/10.1021/ic301923x
Abstract
A porous metal–metalloporphyrin framework, MMPF-6, based upon an iron(III)-metalated porphyrin ligand and a secondary binding unit of a zirconium oxide cluster was constructed; MMPF-6 demonstrated interesting peroxidase activity comparable to that of the heme protein myoglobin as well as exhibited solvent adaptability of retaining the peroxidase activity in an organic solvent.This publication has 53 references indexed in Scilit:
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