Intermolecular energy-band dispersion in PTCDA multilayers
- 18 July 2003
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 68 (3), 033102
- https://doi.org/10.1103/physrevb.68.033102
Abstract
The electronic structure of a well-oriented perylene-3,4,9,10-tetracarboxylic acid-dianhydride multilayer prepared on single crystal surface were studied by angle-resolved ultraviolet photoemission spectroscopy using synchrotron radiation. From the photon energy dependence of normal emission spectra, we observed an intermolecular energy-band dispersion of about 0.2 eV for the highest occupied molecular orbital (HOMO) band of single character. The observed energy-band dispersion showed a cosine curve, which originates from the intermolecular interaction. Analyses using the tight-binding model gave that the transfer integral of about 0.05 eV for the interaction, the effective mass of HOMO hole and the hole mobility This is the first observation of the intermolecular energy-band dispersion of a conventional single-component organic semiconductor only with the weak intermolecular van der Waals interaction.
Keywords
This publication has 22 references indexed in Scilit:
- Intramolecular energy-band dispersion in oriented thin films of n-CF3(CF2)22CF3 observed by angle-resolved photoemission with synchrotron radiationThe Journal of Chemical Physics, 2000
- Angle-resolved ultraviolet photoelectron spectroscopy and theoretical simulation of a well-ordered ultrathin film of tetratetracontane on Cu(100): Molecular orientation and intramolecular energy-band dispersionPhysical Review B, 1999
- Angle-resolved photoelectron spectroscopic study of orientedp-sexiphenyl: Wave-number conservation and blurring in a short model compound of poly(p-phenylene)Physical Review B, 1995
- Electronic structure of 4-BCMU polydiacetylene studied by angle-dependent photoelectron spectroscopySynthetic Metals, 1994
- Electronic structure of alkane chains. Complete one-dimensional band structures of the valence statesChemical Physics Letters, 1994
- One-dimensional band dispersion with a correlation modulated charge densitySolid State Communications, 1992
- Energy-band dispersion in oriented thin films of pentatriacontan-18-one by angle-resolved photoemission with synchrotron radiationPhysical Review B, 1990
- Intramolecular band mapping of n-CH3(CH2)34CH3 over the whole Brillouin zone by angle-resolved photoemissionChemical Physics Letters, 1987
- Valence bands of oriented finite linear chain molecular solids as model compounds of polyethylene studied by angle-resolved photoemissionChemical Physics, 1986
- Intramolecular energy band dispersion of n-C36H74 observed by angle-resolved photoemission with synchrotron radiationChemical Physics Letters, 1984