Rhodium Dinaphthocyclooctatetraene Complexes: Synthesis, Characterization and Catalytic Activity in [5+2] Cycloadditions
- 1 February 2012
- journal article
- Published by Wiley in Angewandte Chemie
- Vol. 51 (11), 2736-2740
- https://doi.org/10.1002/anie.201108270
Abstract
Rh COT in the act: a Ni(0)-catalyzed [2+2+2+2] cycloaddition provides a high-yielding, scalable synthesis of the ligand dinaphtho[a,e]cyclooctatetraene (dnCOT). dnCOT complexation with Rh(I) gives [Rh(dnCOT)(MeCN)(2)]SbF(6), an excellent catalyst for [5+2] cycloadditions of vinylcyclopropanes and π-systems with impressive functional group compatibility.This publication has 66 references indexed in Scilit:
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