The Formation of 1,4-Quinones by Oxovanadium(IV)-Complexes Catalyzed Aerobic Oxygenation of Fused Aromatic Compounds
- 1 May 1994
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 23 (5), 885-888
- https://doi.org/10.1246/cl.1994.885
Abstract
In the presence of a catalytic amount of oxovanadium(IV) complexes coordinated with 1,3-diketone ligands, fused aromatic compounds such as naphthalenes and naphthol derivatives are smoothly oxygenated into the corresponding 1,4-naphthoquinones by combined use of molecular oxygen and crotonaldehyde under an atmospheric pressure.Keywords
This publication has 10 references indexed in Scilit:
- Direct Epoxidation of Olefins Catalyzed by Nickel(II) Complexes with Molecular Oxygen and AldehydesBulletin of the Chemical Society of Japan, 1991
- Metal catalysis in oxidation by peroxides. 31. The hydroxylation of benzene by VO(O2)(PIC)(H2O)2: mechanistic and synthetic aspectsThe Journal of Organic Chemistry, 1989
- Oxidation of Methoxy- and/or Methyl-Substituted Benzenes and Naphthalenes to Quinones and Phenols by H2O2 in HCOOHBulletin of the Chemical Society of Japan, 1989
- Mediated electrochemical synthesis of aromatic aldehydes, ketones, and quinones using ceric methanesulfonateThe Journal of Organic Chemistry, 1989
- Synthetic approaches toward mitomycins: construction of p-quinone moiety on 1-benzazocine derivativeThe Journal of Organic Chemistry, 1988
- A Convenient Synthesis of Juglone Via Neutral Salcomine OxidationSynthetic Communications, 1984
- Heterolytic and Homolytic Oxygen Transfer Reactions from d0 Metal Peroxides to HydrocarbonsIsrael Journal of Chemistry, 1983
- The oxidation of ortho‐xylene on vanadium pentoxide catalysts II. The influence of catalyst support material on product distributionThe Canadian Journal of Chemical Engineering, 1977
- Oxidations with potassium nitrosodisulfonate (Fremy's radical). Teuber reaction.Chemical Reviews, 1971
- The Reaction between Quinones and Sodium Enolates. V. 2,3-Dimethylnaphthoquinone and Sodium Malonic Ester1Journal of the American Chemical Society, 1937