Spin-singlet ground state with energy gaps inCu2PO4: Neutron-scattering, magnetic-susceptibility, and ESR measurements

Abstract

Magnetic properties of ${\mathrm{Cu}}_2{\mathrm{PO}}_4$ powder were studied by neutron-scattering, magnetic-susceptibility, and electron-spin-resonance (ESR) measurements. It has been proved that this cuprate has a spin-singlet ground state separated from the excited states by finite-energy gaps. The spin susceptibility and the ESR integrated intensity show a broad maximum around 100 K followed by a rapid decrease to zero with decreasing temperature. The neutron-scattering measurements clearly exhibit magnetic excitations around 14.4 and 17.9 meV. The excitation energies are nearly temperature and $Q$ independent, but the intensity of the excitations does decrease with increasing temperature. The experimental results are consistent with a model of a four-spin $\mathrm{}(S=1/2\mathrm{})\mathrm{}$ chain with alternating exchange interactions. The two exchange interactions are $J_1=-55$ K (ferromagnetic) and $J_2=95\mathrm{}$ K (antiferromagnetic).